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Title
High School DxDHaisukuru Di Di(ハイスクールD×D)
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Highschool DxD(alternate spelling) 
Released
12 TV episodes, 1 OVA episode12 TV episodes, 1 OVA episode
Dates
August 20, 2013January 6, 2012–March 23, 2012
Company
FUNimationFujimi Shobo, Media Factory, Genco, High School DxD Production Committee
Creator
 Ichiei Ishibumi(石踏 一榮)
Director
 Tetsuya Yanagisawa(柳沢 テツヤ)
Genre
Comedy, Ecchi, RomanceComedy, Ecchi, Romance
Related
High School DxD NEWHaisukuru Di Di NEW
Characters
Rias GremoryRiasu Guremori
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Akeno Himejima ⊕Akeno Himejima ⊕
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-- more listed below ---- more listed below --

Last I checked, this anime was available on DVD at Amazon.

Characters: High School DxD

English Name
Japanese Name
English Name
Japanese Name
Rias Gremory Riasu Guremori Koneko Toujou ⊕ Koneko Toujou ⊕
Akeno Himejima ⊕ Akeno Himejima ⊕ Ravel Phoenix ⊕ --?--
Asia Argento ⊕ Ashia Arujento ⊕ Raynare/Yuma Amano ⊕ Raynare/Yuma Amano ⊕
Freed Sellzen ⊕ --?-- Sirzechs Lucifer ⊕ --?--
Grayfia Lucifuge ⊕ --?-- Xenovia ⊕ Zenovia ⊕
Issei Hyodo ⊕ Issei Hyodo ⊕ Yuto Kiba ⊕ Yuto Kiba ⊕

Description: High School DxD

When Issei Hyodo enrolled in Kuoh Academy, he thought he was in heaven – the unusually-large ratio of girls-to-boys seemed to assure that he would get laid! However, it had been over a year, and all the girls avoided him like the plague! But he was intrigued by one girl – the incredibly-beautiful and busty redhead Rias Gremory, a transfer student from Europe and head of the school's Occult Research Club.

But when a girl named Yuma Amano asked him out, Issei thought his dreams were about to come true! But on their first date, Issei found to his horror that she was, in fact, a fallen angel – and fatally stabbed him! But just as incredible, he was saved by the ravishing Rias – who turns out to be a devil – and turned Issei into her devil servant! Now endowed with new powers, Issei joins Rias and the Occult Research Club in a battle between heaven and hell! Let's just hope his overactive hormones don't get the best of him!